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Iridium/Nickel PhotoRedox Kits

Description:

Photoredox chemistry has been reported in the literature using a wide range of catalysts and reagents. However, often these reactions are highly substrate, solvent and base specific. In order to facilitate the screening of common photochemistry reactions, HepatoChem has released a series of high-throughput photocatalysis reaction screening kits combining common Iridium, Nickel, ligand and base combinations to achieve successful cross-coupling transformations.

Ir/Ni catalysis versatility

Depending on the ligand, base and solvent, the Ir/Ni catalytic systems can perform different cross-coupling reaction.

C-C Coupling

C-N Coupling

C-O Coupling

5 Ir/Ni Kits Available

Ir/Ni Base and Solvent Kit HCK1009-01-002

2 sets of 8 conditions with 8 different bases per kit (16 total vials)

5 µmol of substrates in 100 µl solvent, Ir(dF-CF3-ppy)3(dtbbpy) PF6 (2 mol%), Ni Ligand dtbbpy (10 mol%) and base (3 eq.)

Ir/Ni Base and Ligand Screen Kit 1 HCK1009-01-003

2 sets of 16 conditions with 4 bases and 4 ligands per kit (32 total vials)

5 µmol of substrates in 100 µl solvent, Ir(dF-CF3-ppy)3(dtbbpy) PF6 (2 mol%), Ni Ligand dtbbpy (10 mol%) and base (3 eq.)

Ir/Ni Base and Ligand Screen Kit 2 HCK1009-01-004

2 sets of 24 conditions with 6 bases and 4 ligands per kit (48 total vials)

5 µmol of substrates in 100 µl solvent, Ir(dF-CF3-ppy)3(dtbbpy) PF6 (2 mol%), Ni Ligand dtbbpy (10 mol%) and base (3 eq.)

Ir/Ni Base and Ir Catalyst Screen Kit 1 HCK1009-01-005

2 sets of 18 conditions with 3 bases and 6 Ir catalysts per kit (36 total vials)

5 µmol of substrates in 100 µl solvent Ir catalyst (2 mol%), Ni dtbbpy (10 mol%) and base (3 eq.)

Ir/Ni Base and Catalyst Screen Kit for C-O coupling HCK1009-01-006

2 sets of 8 conditions with 4 different bases, Ir(dF-CF3-ppy)2(dtbbpy)PF6

Ni dtbbpy and quinuclidine per kit (16 total vials).

Iridium Catalysts

Nickel Ligands

dtbbpy

(MeO)2bpy

bphen

biox

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Iridium/Nickel PhotoRedox Kits

Description:

Ir/Ni catalysis versatility

Depending on the ligand, base and solvent, the Ir/Ni catalytic systems can perform different cross-coupling reaction.

C-C Coupling

C-N Coupling

C-O Coupling

5 Ir/Ni Kits Available

Ir/Ni Base and Solvent Kit HCK1009-01-002

2 sets of 8 conditions with 8 different bases per kit (16 total vials)

5 µmol of substrates in 100 µl solvent, Ir(dF-CF3-ppy)3(dtbbpy) PF6 (2 mol%), Ni Ligand dtbbpy (10 mol%) and base (3 eq.)

Ir/Ni Base and Ligand Screen Kit 1 HCK1009-01-003

2 sets of 16 conditions with 4 bases and 4 ligands per kit (32 total vials)

5 µmol of substrates in 100 µl solvent, Ir(dF-CF3-ppy)3(dtbbpy) PF6 (2 mol%), Ni Ligand dtbbpy (10 mol%) and base (3 eq.)

Ir/Ni Base and Ligand Screen Kit 2 HCK1009-01-004

2 sets of 24 conditions with 6 bases and 4 ligands per kit (48 total vials)

5 µmol of substrates in 100 µl solvent, Ir(dF-CF3-ppy)3(dtbbpy) PF6 (2 mol%), Ni Ligand dtbbpy (10 mol%) and base (3 eq.)

Ir/Ni Base and Ir Catalyst Screen Kit 1 HCK1009-01-005

2 sets of 18 conditions with 3 bases and 6 Ir catalysts per kit (36 total vials)

5 µmol of substrates in 100 µl solvent Ir catalyst (2 mol%), Ni dtbbpy (10 mol%) and base (3 eq.)

Ir/Ni Base and Catalyst Screen Kit for C-O coupling HCK1009-01-006

2 sets of 8 conditions with 4 different bases, Ir(dF-CF3-ppy)2(dtbbpy)PF6

Ni dtbbpy and quinuclidine per kit (16 total vials).

Iridium Catalysts

Nickel Ligands

dtbbpy

(MeO)2bpy

bphen

biox

Contact Us!

Interested in learning more about our products?

Complete our short contact form and we'll get back to you as soon as possible.