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Product No: AF0767

Lithium aluminum hydride, 1.0M in THF

Name: Lithium aluminum hydride
Brand: Chempure

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CAS Number

16853-85-3

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IUPAC name	aluminum;lithium;hydride
canonical smiles	[H-].[H-].[H-].[H-].[Li+].[Al+3]
inchi	InChI=1S/Al.Li.4H/q+3;+1;4*-1
inchi key	BJKLPLABXHXMIM-UHFFFAOYSA-N
molecular formula	LiAlH4
synonyms	16853-85-3 aluminum;lithium;hydride LAH Lithium Aluminum Hydride (1M in THF) MFCD00011075
Compound Description	Lithium aluminum hydride appears as a white powder that turns gray on standing. If spread out over a large flat combustible surface, friction can cause ignition. Used to make other chemicals, as a polymerization catalyst, as a hydrogen source, and as a propellant.

Computed Properties

Molecular Weight:	38.0 g/mol
Hydrogen Bond Donor Count:	0
Hydrogen Bond Acceptor Count:	4
Rotatable Bond Count:	0
Exact Mass:	38.0288420 g/mol
Monoisotopic Mass:	38.0288420 g/mol
Topological Polar Surface Area:	0 Å²
Heavy Atom Count:	2
Formal Charge:	0
Complexity:	0
Isotope Atom Count:	0
Defined Atom Stereocenter Count:	0
Undefined Atom Stereocenter Count:	0
Defined Bond Stereocenter Count:	0
Undefined Bond Stereocenter Count:	0
Covalently-Bonded Unit Count:	6
Compound Is Canonicalized:	Yes

Related Compounds

Lithium aluminum tetrahydride

Dialuminum;lithium;hydride

Aluminum;lithium;deuteride

hazard signal	Danger
hazard classes and categories	Substance or mixture which in contact with water emits flammable gas - category 1 Skin corrosion - category 1A Flammable - 2nd degree, Reactive - 2nd degree Water-react. 1 Skin Corr. 1A
precautionary statement codes	P223, P231+P232, P260, P264, P280, P301+P330+P331, P302+P335+P334, P302+P361+P354, P304+P340, P305+P354+P338, P316, P321, P363, P370+P378, P402+P404, P405, and P501
hazard statements	H260: In contact with water releases flammable gases which may ignite spontaneously [Danger Substances and mixtures which in contact with water, emit flammable gases] H314: Causes severe skin burns and eye damage [Danger Skin corrosion/irritation]
hazards summary	Contact with solid causes caustic burns to eyes and skin. Inhalation of high concentrations can cause pulmonary edema. Reacts with moisture on the skin or in the eyes and respiratory tract to form a corrosive alkali solution (lithium hydroxide).

toxicity summary

IDENTIFICATION AND USE: Lithium aluminum hydride is a gray-white monoclinic crystalline material which is soluble in ether, tetrahydrofuran, dimethylcellosolve; partially soluble in dibutyl ether and insoluble in dioxane. This chemical is an intermediate in the production of other hydrides. It is used as a reducing agent for over 60 different functional groups, especially for pharmaceutical, perfume, and fine organic chemicals; converts esters, aldehydes and ketones to alcohols and nitriles to amines; source of hydrogen; propellant; catalyst in polymerizations. HUMAN EXPOSURE AND TOXICITY: Causes severe eye and skin burns. It may be harmful if inhaled. This chemical is irritating to skin, eyes, and respiratory system. Symptoms of overexposure include spasms, inflammation and edema of larynx, and bronchi, pulmonary edema, coughing, wheezing, laryngitis, nausea, and vomiting. Solid will burn skin and eyes. The hydrides of aluminum can react with moisture and leave behind hydroxide. The hydrides of lithium in the presence of moisture are readily converted to hydroxides which are highly irritating to the skin by caustic and thermal action. Similar effects can occur on contact with eyes and respiratory mucous membranes. ANIMAL STUDIES: No animal studies could be located.

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Documentation

Certificate of Analysis

Lot Number

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CAS #

*This document is like a lab demo—an example Certificate of Analysis (COA) that showcases what a COA looks like but may not match the latest batch in all its glory. Think of it as a chemistry experiment: close, but not quite the final reaction!

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About this item

IUPAC name	aluminum;lithium;hydride
canonical smiles	[H-].[H-].[H-].[H-].[Li+].[Al+3]
inchi	InChI=1S/Al.Li.4H/q+3;+1;4*-1
inchi key	BJKLPLABXHXMIM-UHFFFAOYSA-N
molecular formula	LiAlH4
synonyms	16853-85-3 aluminum;lithium;hydride LAH Lithium Aluminum Hydride (1M in THF) MFCD00011075
Compound Description	Lithium aluminum hydride appears as a white powder that turns gray on standing. If spread out over a large flat combustible surface, friction can cause ignition. Used to make other chemicals, as a polymerization catalyst, as a hydrogen source, and as a propellant.

Computed Properties

Molecular Weight:	38.0 g/mol
Hydrogen Bond Donor Count:	0
Hydrogen Bond Acceptor Count:	4
Rotatable Bond Count:	0
Exact Mass:	38.0288420 g/mol
Monoisotopic Mass:	38.0288420 g/mol
Topological Polar Surface Area:	0 Å²
Heavy Atom Count:	2
Formal Charge:	0
Complexity:	0
Isotope Atom Count:	0
Defined Atom Stereocenter Count:	0
Undefined Atom Stereocenter Count:	0
Defined Bond Stereocenter Count:	0
Undefined Bond Stereocenter Count:	0
Covalently-Bonded Unit Count:	6
Compound Is Canonicalized:	Yes

Related Compounds

Lithium aluminum tetrahydride

Dialuminum;lithium;hydride

Aluminum;lithium;deuteride

hazard signal	Danger
hazard classes and categories	Substance or mixture which in contact with water emits flammable gas - category 1 Skin corrosion - category 1A Flammable - 2nd degree, Reactive - 2nd degree Water-react. 1 Skin Corr. 1A
precautionary statement codes	P223, P231+P232, P260, P264, P280, P301+P330+P331, P302+P335+P334, P302+P361+P354, P304+P340, P305+P354+P338, P316, P321, P363, P370+P378, P402+P404, P405, and P501
hazard statements	H260: In contact with water releases flammable gases which may ignite spontaneously [Danger Substances and mixtures which in contact with water, emit flammable gases] H314: Causes severe skin burns and eye damage [Danger Skin corrosion/irritation]
hazards summary	Contact with solid causes caustic burns to eyes and skin. Inhalation of high concentrations can cause pulmonary edema. Reacts with moisture on the skin or in the eyes and respiratory tract to form a corrosive alkali solution (lithium hydroxide).

toxicity summary

symptoms

Product No: AF0767

Lithium aluminum hydride, 1.0M in THF

Product No: AF0767

About this item

NAME AND IDENTIFIERS

CHEMICAL AND PHYSICAL PROPERTIES

Related Compounds

SAFETY AND HAZARDS

TOXICITY

About this item

Documentation

Certificate of Analysis

Require a Sample Certificate of Analysis (COA) ?

Reviews

Product No: AF0767

About this item

NAME AND IDENTIFIERS

CHEMICAL AND PHYSICAL PROPERTIES

Related Compounds

SAFETY AND HAZARDS

TOXICITY

Require a Sample Certificate of Analysis (COA) ?