HCK1006-01-023
(Patent Pending)
The EvoluChem™ PhotoRedOx Duo leverages the same patented concept (US Patent #10,906,022) as the original PhotoRedOx Box. PhotoRedOx Duo increases the reaction vials capacity to 16 vials (2, 4 or 8 ml) using 2 of the same vial holders as the PhotoRedOx box. Using the 2 blue LED setup allows to increase reaction rate of difficult reaction conditions.
In duplicate in a 4-ml vial equipped with a teflon septa and 2×7 mm stir bar, were weighed 4-bromoacetophenone (4.95 mg, 25 µmol) and potassium benzyltrifluoroborate (4.50 mg, 25 µmol, 1 equiv.). To this vial was added a 1.0 ml solution in DMA containing NiCl2-dme (1.1 mg, 5 µmol, 0.1 mol %), dtbbpy (1.3 mg, 5 µmol, 0.1 mol %) and Ir(dF-CF3-ppy)2(dtbpy) (1.12 mg, 1 µmol, 0.02 mol %) followed by addition of 2,6-lutidine (17.5 µl, 150 µmol, 6 equiv.) . The solution was sparged with nitrogen via submerged needle for 5 minutes and vial was placed in EvoluChem photoreactor with blue Kessil 34W LED or reactor with two blue kessil 34W. Reaction time course was monitored at 0, 5, 15, 45, 120, 240, and 360 minutes.
HCK1006-01-017
HCK1006-01-018
HCK1006-01-019
HCK1006-01-020
HCK1006-01-021
Interested in learning more about our products?
Complete our short contact form and we'll get back to you as soon as possible.
